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1. Cliff Lee—As unlikely as it may sound, it would truly be the ideal fifth starter the Braves are in need of. I would not hesitate to classify him as the best free-agent pitcher on the market right now, and he could really do wonders with the Braves.
2. Javier Vazquez—In case you don't remember this guy, I will remind you that in 2009, as a Braves starter, he landed himself in the top five for ERA in the NL.
Despite the letdown he caused in his return as a Yankee last season, it is quite possible that the Braves could regain his contract and shape him up to what they had as before. His contract should be cheap, it is unlikely that other teams will pay much for him.
3. Mike Minor/Brandon Beachy—Each of them was pulled up as a last resort, and neither produced a satisfying performance. Near the end of the year, when injuries were not uncommon, each was pulled up as an unintended September call-up.
I think that with a bit more experience, each could be made into a reliable starter, but for them I would prescribe more time in the minor leagues.