This was an easy choice for No. 1, as it is one of the best memories in recent WWE memory.
RVD had decided to cash in the Money in the Bank briefcase which he won at WrestleMania 22 to challenge John Cena for the WWE title at ECW One Night Stand in 2006. After the success of the One Night Stand event from the previous year, this match needed to deliver.
The stage was set. RVD was in front of the old ECW faithful inside the Hammerstein Ballroom. Cena came in as the hated enemy, as a sign that read "If Cena wins we riot" hung prominently in the stands.
The crowd made this match what it was, giving it a feel that you are rarely privileged enough to be a part of. With interference from Edge and Paul Heyman lending his hand as a referee in the end, RVD defeated Cena to win the WWE title, setting off a frenzied response.
This was not only RVD's most memorable moment, it ranks up there with the best in WWE history.