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This incident may not be as clear in the mind as some of the others on this list and that might be because of the two teams involved, Stoke City and Hull City.
Tigers striker Dean Windass found a way, though not a completely successful one, to try and put off Rory Delap during one of Delap's patented long-range throw-ins.
Windass casually warmed up in the vicinity of Delap during at least two of those throw-in attempts, earning at least one warning and one yellow card, and just the imagery of that brings about a few chuckles.(via Mirror Football)
There's not a video of the actual incident, not one that I could find anyway, but here's a clip, according to the uploader, of what happened before Windass got his yellow card.